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If you report them individually, you don't need to wait a day between the reports. It's best if you report them immediately so the mods can quickly take care of them. You shouldn't have to worry about bombarding the staff with reports. They are here to help you. ^^
However, if you're nervous about doing that, you can pm a mod. However, keep in mind. You do have to provide evidence of those people breaking the rules and you have to keep a mind it may take a bit of time for a mod to get to it if they go offline.
Edit: I'm mostly basing this off my experience with pming mods and reporting users.